There's a huge amount of learning Spanish resources on the internet. Some you have to pay for, some are free. Here's the pick of the free online language learning sites for Spanish as well as other languages:
BBC Languages
Live Mocha
Before You Know It (BYKI)
Bite Sized Languages
busuu.com
My personal favourite is Notes in Spanish, which is a set of mp3 podcasts that you can listen to on your ipod on the way to work etc.
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